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Beilstein J. Org. Chem. 2019, 15, 2534–2543, doi:10.3762/bjoc.15.246
Graphical Abstract
Figure 1: Well-defined catalysts for alkyne metathesis.
Figure 2: Examples for a ferrrocenic thiacrown ether complexing palladium (IV), and a dicationic ferrocenopha...
Scheme 1: Synthesis of substrates 1 (a n = 2; b n = 3) via esterification of 3 and following RCAM with cataly...
Figure 3: ORTEP diagram of 1a with thermal displacement parameters drawn at 50% probability; hydrogen atoms a...
Figure 4: ORTEP diagram of 1b with thermal displacement parameters drawn at 50% probability; hydrogen atoms a...
Figure 5: ORTEP diagram of 2a with thermal displacement parameters drawn at 50% probability; hydrogen atoms a...
Figure 6: ORTEP diagram of 2b (one of two molecules of the asymmetric unit) with thermal displacement paramet...
Figure 7: Cyclic voltammogram of 2a in DCM, 0.2 M n-Bu4NPF6, 1 V s−1 scan rate, referenced vs FcH/FcH +.
Scheme 2: Top: Oxidation of ferrocenophane 2a to the corresponding ferrocenium cation 4 with Ag(SbF6) in DCM ...
Figure 8: ORTEP diagram of 4 with thermal displacement drawn at 50% probability; hydrogen atoms are omitted f...
Figure 9: 1H NMR (200.1 MHz, 298 K) spectrum of top: 2a in CDCl3; bottom: 5 in THF-d8 – signals for solvate T...
Figure 10: ORTEP diagram of 5(thf) with thermal displacement drawn at 50% probability; hydrogens atoms, [SbF6]−...
Beilstein J. Org. Chem. 2018, 14, 2425–2434, doi:10.3762/bjoc.14.220
Figure 1: Selected homogeneous catalysts for alkyne metathesis.
Scheme 1: Synthesis of alkylidyne complex V from bimetallic [(t-BuO)3W≡W(Ot-Bu)3]; the catalytically active d...
Scheme 2: Synthesis of hexakis(fluoroalkoxide) dimers Mo2F6 [73] and W2F3.
Figure 2: Molecular structure of W2F3·NHMe2 with thermal displacement parameters drawn at 50% probability. Hy...
Scheme 3: Preparation of the alkylidyne complex WPhF3.
Figure 3: Molecular structure of WPhF3 with thermal displacement parameters drawn at 50% probability. Hydroge...
Scheme 4: Self-metathesis of 1-phenyl-1-propyne derivatives by tungsten complexes W2F3 and WPhF3.
Figure 4: Conversion versus time diagram for the self-metathesis of 1-phenyl-1-propyne catalyzed by 0.5 mol % ...
Beilstein J. Org. Chem. 2011, 7, 82–93, doi:10.3762/bjoc.7.12
Scheme 1: Alkyne metathesis based on the Katz mechanism.
Scheme 2: Reaction patterns of alkyne metathesis.
Scheme 3: Typical examples from traditional catalyst systems.
Scheme 4: Ligand synthesis and catalyst design.
Scheme 5: Catalysts synthesis using high- and low-oxidation-state routes (for 6a, X = Li or K; for 6b, X = K)....
Figure 1: Alkylidyne complexes 9 and 10.
Scheme 6: Design strategy of Fürstner’s new system.
Scheme 7: Synthetic routes of Fürstner’s new catalysts.
Scheme 8: Lewis acid addition of 26 and 28.
Scheme 9: Preparation of the silanolate–alkylidyne tungsten complex 39.